Page 10 - Open Access-June 2019
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120
 Percentage residual compressive strength
              100
                                                                       100
                                                                                                                                100
 100
                                                                                                                                80
                                                                       80
               80
 80
                                                                                                                                                                         M 90
 M 90
                                                                                                                 M90
                                                        M 90
               60
 60
                                                                                                                                60
                                                                       60
               40
                                                                                                                                40
 40
                                                                       40
 0  5  10  15  20  25  30  35  40  45  50  M 30  Percentage residual compressive strength  120  0  5  10  15  20  25  30  35  40  45  50  M 30  Percentage residual compressive strength  120  0  5  10  15  20  25  30  35  40  45  50  M30  Percentage residual compressive strength  120  0  5  10  15  20  25  30  35  40  45  50  M 30
 No. of cycles                No. of cycles                                           No. of cycles                                               No. of cycles
            TECHNICAL PAPER
                                                                with increasing hydration until full hydration is reached. The   7 6
 Percentage residual compressive strength  100  100  C  Percentage residual compressive strength  100  100  C  Weight loss measurements monitor the moisture migration   M 30   Percentage weight loss  5 4 3 2  M 30
                                                                       7
 120
              120
                                                                evaporation of capillary water and gel water in concrete at high
                                                                       6
                                                                temperature is monitored by recording weight loss over time.
                                                                     Percentage weight loss
                                                                       5
                                                                at various structural levels, from macro to micro. Weight loss
                                                                       4
                                                                of concrete at high temperatures greatly depends on the
               80
 80
                                                       200  C
 200  C
                                                                       3
                                                                composition (cement type and content, water content, water/
                                                       300  C
 300  C
                                                                cement ratio, aggregate type and contents), hydration degree
               60
                                                                       2
 60
                                                                                                                 M 90
                                                                                                                                                                          M 90
                                                       400  C
 400  C
                                                                (curing temperature, humidity and age) and the initial moisture
                                                                       1
                                                                heating scenarios, e.g. heating temperature, heating rate,
                                                                       0
 40
                                                                                      20
                                                                            5
                                                                                   15
                                                                               10
                                                                                                   40
                                                                                                35
                                                                                                          50
                                                                                                       45
                                                                                             30
                                                                         0
                                                                                         25
 0  5  10  15  20  25  30  35  40  45  50  40  0  5  10  15  20  25  30  35  40  45  50  states (saturated, air-dried or oven-dried). It also depends on   1 0  0  5  10  15  20  25  30  35  40  45  50
                                                                exposure time etc. This result is in good agreement with the
                                                                                      No. of cycles
 No. of cycles               No. of cycles                      findings of Brovwers (1948; 2003; 2004) and Taylor (1986).                        No. of cycles
           Figure 4.6: Variation of percentage residual compressive strength of
                    M 90 specimens exposed to temperature.      Weight loss is a continuous non-reversible process to represent
                                                                moisture migration in the concrete. The structural integrity of
                                                                       8
 7             8                                                the specimens deteriorates as confirmed by the increase in      7
         4.2 Effect of thermal cycles on weight loss
                                                                       7
               7
 6 5     Weight reduction takes place in the specimens at all   weight reduction with increased temperature. The reduction in   6 5
                                                                weight confirms the loss of mass by the concrete material and
                                                                     Percentage  weight loss
 Percentage weight loss  120 120  M 30  of the release of bound water from the cement paste, air   M 30  loss of the concrete specimens will estimate the durability of  100  C  Percentage weight loss  4 3 2  100  C
                                                                       6
               6
            Percentage weight loss
         temperatures of exposure due to the release of water. Because
                                                                the increase in the proportion of air voids. The study of weight
                                                                       5
               5
 4
         voids are formed in the concrete. So water plays a major role
               4
                                                                       4
                                                                concrete. Higher heating temperature always led to a higher
                                                                                                                                                                         200  C
                                                                                                                200  C
 3
         in determining the nature and influencing the behaviour and
                                                                     120 3
                                                                weight loss which makes the concrete less durable.
 120
 120
            120
 Percentage residual compressive strength Percentage residual compressive strength  100 100  M 30  Percentage residual compressive strength Percentage residual compressive strength  100 100 1 0 80  0  5  10  15  20  No. of cycles  40  45  50  M 30  bound water. Capillary water is evaporable water and exists not   loss with number of thermal cycles for the concrete specimens of   1 0  0  5  10  15  No. of cycles  35  40  45  50
              120 3
                                                                   Percentage residual compressive strength
                                                                       120
                                                                    Percentage residual compressive strength
            Percentage residual compressive strength
          Percentage residual compressive strength
                                                                                                                                                                         300  C
                                                                                                                300  C
         performance of concrete. There are three different types of
                                                        M 90
 2
 M 90
                                                                       2
               2
                                                                                                                                                                         400  C
                                                                                                                400  C
                                                                1. Figure 4.7, 4.8, 4.9 and 4.10 show the variation of % weight
         water in concrete: capillary water, gel water and chemically
            100
                                                                     1001
                                                                       100
              100 1
                                                                       0
               0
                                                                M 30 and M 90 grade heated from ambient temperature to 100,
         only in capillary pores of cement paste but also in aggregates
                                                                                                                                                 25
                                                                                                                                              20
                             20
                                                                                                                                                     30
                                                                                                   40
                    5
                          15
                       10
                                 25
                                                                         0
                                           40
                                                 50
                                              45
                                    30
                                                                                                         50
                                       35
                                                                            5
                                                                               10
                                                                                      20
                                                                                                      45
 35
 25
 30
                                                                                               35
                                                                                  15
                 0
                                                                                         25
                                                                                            30
         and at interface. It can easily evaporate when the ambient
                                                                200, 300, 400°C respectively. In the case of M 30 grade concrete
 80
 80
             80
               80
                                                                        80
                                                                      80
 80
                                                                                                               M 30
                                                                                                                M 30
 M 30
                                                                                     No. of cycles
                             No. of cycles
                                                                exposed to 100°C, the % weight loss increased from 3.29% at
         temperature is high. Gel water exists in the gel pores of
                                                        M30
                                                      M30
 M 30
                                                                                                               M 90
 M 90
                                                                                                                M 90
 M 90
         cement paste. It is generally regarded as adsorbed water or
                                                                first cycle to 5.23% after 50 cycles. In the case of M 90 grade
                                                      M90
                                                        M90
 M 90
 M 90
               60
 60
 60
             60
                                                                      60
 60
                                                                        60
 60
                                                                3.43% after 50 cycles. A similar trend was observed at remaining
         to the restriction of van der Waals forces with the cement gel
                                                                temperatures. It can be seen that weight loss increased with
         particles. Chemically bound water is the part of cement hydrate
 40
                                                                      40
             40
                                                                        40
 40
               40
                                                                         0
                                    3035
                                       3540
                                          4045
                                                                                                3540
                                                                                             3035
                                                                                          2530
 0  0 5  510 1015 1520 2025  2530 3035 3540 4045 4550 50  40 40 0  0 5  5 10  1015 1520 2025 2530 3035 3540 4045 4550 50  physically bound water and does not evaporate easily due   concrete, the % weight loss increased from 1.86% at first cycle to
                                                                                                      4550
                                                                                                   4045
                                                                              5 10
                                                                          0 5
                                              4550
                                                                                      2025
                                                                                   1520
                                                                                1015
                    5 10
                          1520
                              2025
                                 2530
                       1015
                 0 5
                0
                                                                                                         50
                                                 50
                                                                increase in thermal cycles irrespective of grade of concrete. But
         compounds and takes up about 23% by weight of anhydrous
 No. of cycles  No. of cycles  No. of cycles                                           No. of cycles
 No. of cycles
                             No. of cycles
 No. of cycles
                                                                                         No. of cycles
         cement. Capillary water content in concrete continuously   weight loss in M 90 grade concrete was low compared to M 30
         decreases but gel and chemically bound water contents increase   grade due to its dense structure.
 Percentage residual compressive strength Percentage residual compressive strength  100 100  100  C  Percentage residual compressive strength Percentage residual compressive strength  100 100  100  C  Percentage weight loss Percentage weight loss  6 5 4 3 2  6 5 4 3 2  M 30   Percentage weight loss  Percentage weight loss  6 5 4 3 2  6 5 4 3 2  M 30
             7
              7
 120
                                                                     7
                                                                       7
 120
 120
 120
 100  C
 100  C
 80
 80
 80
 80
 200  C
 200  C
 200  C
 200  C
                                                        M 30
                                                                                                                 M 30
 300  C
 300  C
 300  C
 300  C
 60
 60
 60
                                                      M 90
                                                        M 90
 60
                                                                                                               M 90
                                                                                                                 M 90
 400  C
 400  C
 400  C
 400  C
 40
 40
 0  0 5  5 10 1015 1520 2025 2530 3035 3540  4045 4550 50  40 40 0  0 5  5 10 1015 1520 2025 2530 3035 3540 4045 4550 50  1 0  1 0 0  0 5  5 10 10 15  15 20 20 25 25 30 30 35 35 40 40 45 45 50 50  1 0  1 0 0  0 5  5 10 10 15 15 20 20 25 25 30 30 35 35 40 40 45 45 50 50
                             No. of cycles
 No. of cycles  No. of cycles  No. of cycles                                           No. of cycles
 No. of cycles
 No. of cycles
                                                                                         No. of cycles
             Figure 4.7: Variation of percentage weight loss of M 30 & M 90   Figure 4.8: Variation of percentage weight loss of M 30 & M 90
                  specimens exposed to a temperature of 100°C.           specimens exposed to a temperature of 200°C.
 7  7  8  8  8  8                                                    7  7
             7
              7
 6 5  6 5  7 6  7 6  14  The IndIan ConCreTe Journal | June 2019     6 5  6 5
 Percentage weight loss Percentage weight loss  4 3  4 3  M 30  Percentage weight loss Percentage weight loss  5 4 3  5 4 3  M 30  Percentage  weight loss Percentage  weight loss  5 4 3  5 4 3  100  C  Percentage weight loss Percentage weight loss  4 3  4 3  100  C
              6
             6
                                                                                                                100  C
                                                       100  C
                                                                                                              200  C
                                                                                                                200  C
                                                     200  C
                                                       200  C
 M 30
 M 30
                                                                                                              300  C
                                                     300  C
                                                                                                                300  C
                                                       300  C
 M 90
 M 90
                                                                                                                400  C
                                                       400  C
 1 2  2 1  M 90  2 1  2 1  M 90  2 1  2 1            400  C          2 1  2 1                                 400  C
 0  0  0  0  0  0                                                    0  0
 0  0 5  5 10 10 15 15 20 20 25 25 30  30 35 35 40 40 45 45 50 50  0  0 5  5 10 10 15 15 20 20 25 25 30 30 35 35 40 40 45 45 50 50  0  0 5  5 10 1015 1520 2025  2530 3035 3540 4045 4550 50  0  0 5  5 10 1015 1520 2025 2530 3035 3540 4045 4550 50
                             No. of cycles
                                                                                     No. of cycles
 No. of cycles
 No. of cycles  No. of cycles  No. of cycles                                       No. of cycles
 No. of cycles
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