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TECHNICAL PAPER


           ENHANCING SERVICE LIFE OF


           PRESTRESSED CONCRETE


           STRUCTURES BY USING


           FLY ASH AND CORROSION


           INHIBITORS                                                                         DYANA JOSELINE*

                                                                                              RADHAKRISHNA G. PILLAI





           Abstract                                               Cl th   :   Critical chloride threshold
                                                                  PS      :  Prestressing
           Seven-wire strands in pretensioned concrete (PTC) structures   RC   :   Reinforced concrete
           can undergo chloride-induced localized corrosion. The corrosion   CIA   :   Corrosion inhibiting admixture
           products occupy the space between the wires of the strands and   hr   :   High resistivity
           do not exert expansive stresses onto the surrounding concrete.   lr   :   Low resistivity
           Hence, propagation of such corrosion cannot be identified/
           detected on time using visual observation of concrete surfaces   %bwob   :   % by weight of binder
           and can lead to catastrophic failure. This scenario necessitates   CE   :   Counter electrode
           technologies to significantly enhance the chloride-resistance and   WE   :   Working electrode
           corrosion-resistance of PTC systems. This paper quantifies the   RE   :   Reference electrode
           role of pulverised fuel ash (PFA; fly ash) and corrosion inhibiting   EIS   :   Electrochemical impedance spectroscopy
           admixtures (CIAs) in enhancing the probabilistic service life.   S-C  :  Steel-cementitious
           For this, lollipop specimens with embedded prestressing steel   TMT   :   Thermo-mechanically treated
           (five in each category) were prepared and subjected to wet-dry   QST    :   Quenched and self-tempered
           exposure using simulated concrete pore solution containing   R p   :   Polarization resistance
           3.5% NaCl, and the chloride threshold (Cl th ) was determined.   :   Corrosion rate during passive-to-active transition
                                                                  i corr, P-A
           Also, the synergistic effects of chloride diffusion coefficient   :   Probability of the occurrence of depassivation
                                                                  P dep
           (D Cl ) and Cl th  on the corrosion-free service life of PTC systems   x   :   Travel length of chlorides (say, cover depth, d)
           are demonstrated. The paper also demonstrates the need
                                                                  t SL    :   Design service life
           for specifying both strength and durability requirements (say,
                                                                  P o     :   Target failure probability
           “Mx-Dy” concrete). Such an approach can aid engineers          :   Initial chloride concentration
           and designers in making informed choices of materials to   Cl i
           achieve protection of PTC systems against chloride-induced   Cl s   :   Surface chloride concentration
           corrosion and to achieve service life of 100+ years with minimal   erfc()   :   Mathematical error function
           maintenance/repair cost.                               %bwoc   :   % by weight of concrete
                                                                          :   Compressive strength of concrete
                                                                  f c
           Keywords: Bridge, Chloride threshold, Corrosion, Corrosion   Mx-Dy   :   A notation to specify concrete
           inhibitors, Fly ash, Prestressed concrete, Service life.
                                                                  1.  INTRODUCTION
           SYMBOLS AND NOTATIONS
                                                                  Significant proportion of the world’s bridge stock comprises of
           PTC     :  Pretensioned concrete
                                                                  pre-tensioned concrete (PTC) members, and these important
           SLD     :   Service-life based design
                                                                  and expensive bridges are expected to be serviceable for a
           D Cl    :   Chloride diffusion coefficient at 28 days  ‘deemed-to-satisfy’ service life of more than 100 years. However,
           SCMs    :   Supplementary cementitious materials       some of them have started showing signs of premature
           PFA     :   Pulverized fuel ash                        corrosion-induced distress. Also, because most of the PTC


        54    THE INDIAN CONCRETE JOURNAL | NOVEMBER 2020
                                                                 *Corresponding author : Dyana Joseline, Email: dyanajoseline@gmail.com
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