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TECHNICAL PAPER


           across different dosages, excess water, particle sizes, animal   fall probability. Further investigation in this direction is needed
           dung, processing techniques, freshness of dung, and age of the   to evaluate walking comfort with the reduced elasticity or to
           prepared powder. The consistency of results across repeated   engineer pavement with similar elasticity.
           testing helped demonstrate the application of cow dung as a
           foaming agent.                                         3.3.4  Fine bone china ceramic aggregates

           Limitations: Due to high moisture content, the foaming   Fine bone china is a high-strength ceramic with high Ca
                                                                              [20]
                                                       3
           agent failed to demonstrate densities below 1200 kg/m  or   (>20 %) content . In general, powdered wastes with high Ca
           compatibility with steam curing. Furthermore, the developed   content show a good pozzolanic reactivity. However, fine bone
           foaming also alters the strength development in the prepared   china is one observed exception where the waste performs
           mixes, limiting the scope of its application. At higher dosages,   better as an aggregate than SCM. As an SCM, fine bone china
           early age strength development is delayed. While it is   ceramic powder can be used as a 20 % substitute for cement.

           speculated to be a result of Ca  distribution due to a higher   At higher dosage, the high volume of P 2 O 5 (>10 %) starts
                                   2+
           effective w/c ratio, the specific mechanism is under further   affecting the pozzolanic activity. As a fine aggregate, fine bone
           investigation. Due to lower early age strength, for mortars with   china can replace up to 60 % of natural sand without showing
                                                                                                           [20]
                                3
           a density below 1600 kg/m  demoulding period increased from   any detrimental effect on the properties of concrete . The
           16 h to up to 40 h. Cow dung has shown an additional property   fine bone china aggregate supports nucleation, or C-S-H gel
           of internal curing with up to 90 % strength in the absence of   deposition, around the ITZ and improves the microstructure of
                                                                                          [21]
           external curing, as opposed to 60 % strength in control samples.   concrete, as shown in Figure 7 .
           Further investigations are needed to optimise the application of   The resulting concrete shows better strength (compressive,
           cow dung as an internal curing agent.
                                                                  flexural, split tensile), residual performance after fire exposure,
           3.3.3  Waste tyre rubber and its specialised           impact resistance, sulphate resistance, chloride resistance,
                                                                                                 [20,22–27]
           application                                            abrasion resistance and acid resistance  . Although
                                                                  the strength improvement can be observed up to 100 %
           Waste tyre rubber has been upcycled in concrete in the form   replacement, more than 60 % is not recommended due to
                                                                                 [20]
                                       [14]
           of crumbs, chips, powder and fibres . The addition of tyre   reduced workability . Overall, the fine bone china ceramic
           rubber is typically detrimental to the compressive strength of   aggregate can be used as a partial substitute for sand to
                                                         [11]
           the concrete and not recommended for most applications .   develop high-performance concrete.
           Interestingly, the addition of waste tyre rubber in fibre form   Key contributions: Extensive investigations were conducted
           improves the flexural strength, energy absorption capacity   to demonstrate the suitability of fine bone china ceramic
           and surface friction of concrete, suitable for pavement
           applications [15-18] . For different compositions of rubber fibre-  aggregates as a sustainable replacement for natural river sand.
           added concrete, as compared to control, energy absorption   While new scientific insights were not observed, the studies
           can be increased by up to 30 % in terms of drop impact,   validated the role of Ca towards nucleation and microstructural
           energy absorbed till the first crack can be increased by up to   improvement.
           five times, and abrasive wear can be reduced by about 45 %,   Limitations: The observed improvements in the microstructure
           implying better material durability [15-18] . Furthermore, the friction   are attributed to the presence of higher Ca content, based
           coefficient can be increased by 0.15, resulting in reduced slip   on an extensive literature review. No suitable experiment
           and fall probability. At the same time, energy absorbed results   was identified to validate whether any other factor played a
           in reduced rebound energy, which can reduce the fall-related   contributing role towards the microstructural improvement.
           injuries . The improvement in energy absorption and abrasive
                [18]
           resistance can also be observed for rubberised ash, obtained
           after pyrolysis of tyre rubber . However, the efficacy of rubber   4.  RHEOLOGY
                                 [19]
           ash is lower than the fibres [18,19] .                 The understanding of the rheology of cement composites
                                                                  is derived from observations on non-hydrating colloids and
           Key contributions: Extensive investigations were conducted
           to identify viable applications for waste tyre rubber. While   suspensions. The hydration of cement affected properties
           some of the scientific insights have been previously reported,   over time, making it difficult to separate the effect of different
                                                                                                                  [28]
           studies related to friction and the proposed anti-slip pavement   factors on the rheological properties at a given point in time .
           applications are novel.                                Often, the rheology of cement was reported as a contradictory
                                                                                               [28]
                                                                  phenomenon across different studies . This limited a
           Limitations: The use of rubber also reduces the elasticity of the   generalised understanding of rheology and its application for
           concrete, which can affect walking comfort and increase the   advanced applications like 3D printing. The gap in fundamental


        72    THE INDIAN CONCRETE JOURNAL | JANUARY 2026
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